Chemistry Journal of Moldova

TRINUCLEAR MIXED-VALENT MANGANESE COMPLEX WITH NON-SCHIFF-BASE TETRADENTATE LIGAND SHOWING A FERROMAGNETIC COUPLING

Author(s):

Masahiro Mikuriya, Iyo Matsushima, Daisuke Yoshioka


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2017 Volume 12, no.2
Pages: 34-40
Keywords:

manganese complex, trinuclear complex, magnetic property, ferromagnetic interaction, mixed-valent complex.


Full Text (PDF): Download
 
 
Abstract (PDF)
Graphical Abstract: Mixed-valent trinuclear manganese complex with N,N’-bis(2-hydroxy-3,5-dimethylbenzyl-N,N’-dimethyl-1,2-ethanediamine (H2hdde), [Mn3(hdde)2(CH3CO2)2(CH3O)2], was synthesized.  The X-ray crystal structure analysis revealed a linearly arrangement of MnIII-MnII-MnIIIcore, where a ferromagnetic coupling (J = 2.62 cm–1) between the MnIII and MnII ions.


 


Downloads: 55