Chemistry Journal of Moldova

SYNTHESIS AND CRYSTAL STRUCTURE OF A NEW Fe(II) α-DIOXIMATE WITH TRIAZINE

Author(s):

О. Ciobanica, P. Bourosh, О. Bologa, I. Bulhac, V. Lozan, V. Shofransky


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2013 Volume 8, no.1
Pages: 78-82
Keywords:

synthesis; Fe(II)dioximate; 1,3,5-triazine, crystal structure.


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Abstract (PDF)

DOI:
dx.doi.org/10.19261/cjm.2013.08(1).09

Graphical Abstract:
The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyioxime, Py-pyridune) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]·2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding.




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