Chemistry Journal of Moldova

SYNTHESIS AND CHARACTERISATION OF A NOVEL PHOSPHONATE LIGAND AND ITS PALLADIUM(II) COORDINATION COMPOUND

Author(s):

Olesea Cuzan


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2017 Volume 12, no.1
Pages: 74-80
Keywords:

palladium, coordination compounds, phosphonate ligands, X-ray characterization.


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DOI:
 dx.doi.org/10.19261/cjm.2016.370

Abstract (PDF)
Graphical Abstract:
 The novel N-(methylene-2-pyridine)-N,N-bis(diethoxyphosphorylmethyl)amine ligand (L) was obtained through a double Kabachnik-Fields reaction, starting from 2-aminomethyl pyridine (2-picolylamine). Based on the L ligand, a new palladium(II) coordination compound [Pd(L)2Cl2] has been synthetized and comprehensively characterized by spectroscopic methods (1H NMR, UV-Vis), ESI mass spectrometry and X-ray crystallography.



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