Chemistry Journal of Moldova
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1. SONOCHEMICAL SYNTHESIS OF HEMATITE
NANOPARTICLES
Mihail Iacob
(downloads: 804)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 474)
3. ROLE OF CYCLODEXTRINS IN NEW
ANTIMYCOBACTERIAL FORMULATIONS
Veaceslav Boldescu, Fliur Macaev, Gheorghe Duca
(downloads: 378)
4. SYNTHETIC TRANSFORMATIONS OF
ENT-KAURENOIC ACID
Olga Morarescu
(downloads: 332)
5. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
(downloads: 312)
NANOPARTICLES
Mihail Iacob
(downloads: 804)
2. SYNTHESIS OF DIFFERENT STRUCTURAL TYPES
OF ZEOLITES IN THE
HALLOYSITE-DOLOMITE-OBSIDIAN SYSTEM
Gunel Mamedova
(downloads: 474)
3. ROLE OF CYCLODEXTRINS IN NEW
ANTIMYCOBACTERIAL FORMULATIONS
Veaceslav Boldescu, Fliur Macaev, Gheorghe Duca
(downloads: 378)
4. SYNTHETIC TRANSFORMATIONS OF
ENT-KAURENOIC ACID
Olga Morarescu
(downloads: 332)
5. STUDIES ON THE WATER SOLUBILIZATION
PROCESSES OF OENOTANNINS AND THEIR
PHYSICO-CHEMICAL PROPERTIES
Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
(downloads: 312)
STABILIZATION OF UNUSUAL SUBSTRATE COORDINATION MODES IN DINUCLEAR MACROCYCLIC COMPLEXES
Author(s):
Field: Inorganic and coordination chemistry
Type: Review
Issue: 2010 Volume 5, no.1
Pages: 24-35
Keywords:
Full Text (PDF): Download
DOI: dx.doi.org/10.19261/cjm.2010.05(1).02
Graphical Abstract: The steric protection offered by the macrobinucleating hexaazaditiophenolate
ligand (L) allows for the preparation of the first stable dinuclear nickel(II) borohydride bridged complex, which reacts rapidly with elemental sulphur producing a tetranuclear nickel(II) complex [{(L)Ni2}2(μ-S6)]2+ bearing a helical μ4-hexa- sulfide ligand. The [(L)CoII 2]2+ fragment have been able to trap a monomethyl orthomolybdate in the binding pocket. Unusual coordination modes of substrate in dinuclear macrocyclic compounds was demonstrated.
Downloads: 18
Vasile Lozan
Field: Inorganic and coordination chemistry
Type: Review
Issue: 2010 Volume 5, no.1
Pages: 24-35
Keywords:
coordination chemistry, borohydride, hexasulphide, molybdate, amino-thiophenolate ligands.
Full Text (PDF): Download
DOI: dx.doi.org/10.19261/cjm.2010.05(1).02
Graphical Abstract: The steric protection offered by the macrobinucleating hexaazaditiophenolate
ligand (L) allows for the preparation of the first stable dinuclear nickel(II) borohydride bridged complex, which reacts rapidly with elemental sulphur producing a tetranuclear nickel(II) complex [{(L)Ni2}2(μ-S6)]2+ bearing a helical μ4-hexa- sulfide ligand. The [(L)CoII 2]2+ fragment have been able to trap a monomethyl orthomolybdate in the binding pocket. Unusual coordination modes of substrate in dinuclear macrocyclic compounds was demonstrated.Downloads: 18