Chemistry Journal of Moldova

NEW N-GLUCOSYLATED SUBSTITUTED ANILINES

Author(s):

Vsevolod Pogrebnoi


Field: Organic chemistry
Type: Research paper
Issue: 2015 Volume 10, no.2
Pages: 62-67
Keywords:

N-glucosylated anilines, (+)-D-glucose, 4-chloroaniline, 3,5-dibromoaniline, Convolutamydines A-E.


Full Text (PDF): Download
Abstract (PDF)

DOI:
dx.doi.org/10.19261/cjm.2015.10(2).08

Graphical Abstract:
 The reaction of (+)-D-glucose with 4-chloroaniline or 3,5-dibromoaniline leads almost exclusively to the β-configuration of glucosylated anilines. The acetylating of 2-(3,5-dibromophenylamino)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol is less selective than in case of the 2-(4-chlorophenylamino)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol.


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