Chemistry Journal of Moldova

MIXED-METAL COMPLEXES OF MIXED-VALENT DINUCLEAR RUTHENIUM(II,III) CARBOXYLATE AND TETRACYANIDONICKELATE(II)

Author(s):

Masahiro Mikuriya, Yusuke Tanaka, Daisuke Yoshioka, Makoto Handa


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2014 Volume 9, no.1
Pages: 93-99
Keywords:

dinuclear ruthenium(II,III) carboxylate; magnetic property; mixed-metal complex; tetracyanido nickelate(II)


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Abstract (PDF)

DOI:
dx.doi.org/10.19261/cjm.2014.09(1).11

Graphical Abstract:
 Mixed-metal chain complexes constructed from lantern-type dinuclear ruthenium(II,III) carboxylate unit and tetracyanidonickelate(II), (PPh4)n[Ru2(O2CCH3)4Ni(CN)4]n•nH2O (1) and (PPh4)n[Ru2{O2CC(CH3)3}4]3n[Ni(CN)4]2n•2nH2O (2), where very weak antiferromagnetic interaction is operating, were synthesized and characterized by elemental analysis and IR and UV-vis spectroscopies and temperature dependence of magnetic susceptibilities (4.5—300K). 




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