Chemistry Journal of Moldova

DINUCLEAR NICKEL(II) PIVALATE WITH µ-AQUA AND DI-µ-PIVALATO BRIDGES SHOWING A FERROMAGNETIC INTERACTION

Author(s):

Masahiro Mikuriya, Melissa Schumacher, Chinatsu Kawano, Takahiro Akihara, Kenta Ono, Daisuke Yoshioka, Hiroshi Sakiyama, Makoto Handa


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2014 Volume 9, no.2
Pages: 62-66
Keywords:

nickel complex, dinuclear complex, magnetic property, ferromagnetic interaction


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Abstract (PDF)

DOI:
dx.doi.org/10.19261/cjm.2014.09(2).09

Graphical Abstract: 
Dinuclear nickel(II) pivalate with µ-aqua- and di-µ-pivalato-bridges having monodentate pivalato and monodentate pivalic acid molecules, [Ni2{O2CC(CH3)3}4(OH2){HO2CC(CH3)3}4], was prepared and characterized by elemental analysis and IR and UV-Vis spectroscopies, temperature dependence of magnetic susceptibilities (4.5—300K), and single-crystal X-ray crystallography. The magnetic data analysis showed a ferromagnetic interaction between the two nickel atoms.


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