Chemistry Journal of Moldova

CRYSTAL STRUCTURE OF {[La2(CNCH2COO)6(H2O)4]H2O}n COMPLEX

Author(s):

Ana Lazarescu, Elena Melnic, Sergiu Shova, Victor Kravtsov, Constantin Turta


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2015 Volume 10, no.1
Pages: 52-56
Keywords:

coordination polymers, lanthanum (III), cyanoacetic acid, crystal structure.


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Abstract (PDF)

DOI:
dx.doi.org/10.19261/cjm.2015.10(1).07

Graphical Abstract:
 A lanthanum(III) cyanoacetate complex  {[La2(CNCH2COO)6 (H2O)4]∙H2O}n (1) was synthesized and characterized by X-ray single-crystal analysis. The complex 1 exhibits one-dimensional coordination polymer structure. Cyanoacetate ligands coordinated in the bidentate bridging and tridentate-chelating bridging modes. The cyano-group of ligand is not coordinated to the lanthanide ion.

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