AZOLIGANDS AS BRIDGED IN MACROCYCLIC DINICKEL COMPLEXES
Author(s): Vasile Lozan
Field: Inorganic and coordination chemistry
Type: Review
Issue: 2010 Volume 5, no.1
Pages: 7-23
Keywords: coordination chemistry, structures, azoligands, nickel macrocyclic complexes, amino-thiophenolate ligands.
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DOI: dx.doi.org/10.19261/cjm.2010.05(1).01
Graphical Abstract: The coordination chemistry of dinickel macrocyclic

hexaamine-dithiophenolate complexes of Robson-type with azoligands is presented in this microreview. All complexes have been characterised by IR-,UV/Visspectroscopy, and X-ray crystallography. The bioctahedral transition metal complexes of the type [(L
6)Ni
2(μ-L')]
+ exhibit a rich coordination chemistry since the active coordination site L' is accessible for a wide range of exogenous coligands.
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