Chemistry Journal of Moldova

A REACTION OF 4, 5-DIPHENYLIMIDAZOLE NITRATION IN THE PRESENCE OF SOME 3D-METALS NITRATES

Author(s):

I. Voda, V. Druta, C. Indricean, I. Ciumacov, C. Turta


Field: Inorganic and coordination chemistry
Type: Research paper
Issue: 2012 Volume 7, no.2
Pages: 124-129
Keywords:

solvothermal synthesis; Cobalt(II), Nickel(II), Zinc(II) complexes; 4,5-diphenyl-2-nitroimidazole, physico- chemical properties.


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Abstract (JPEG)

DOI:
dx.doi.org/10.19261/cjm.2012.07(2).05

Graphical Abstract:
 By interaction of cobalt(II), nickel(II), or zinc(II) nitrate with 4,5- diphenylimidazole in methanol in solvotermal conditions the new derivative of imidazole (4,5-diphenyl-2-nitroimidazole) and three new coordinative compounds [M(4,5-Ph2ImNO2)2(CH3OH)2] have been synthesized and investigated. Metal ions have a distorted octahedral environment with N2O4. Coordination number of metal is six. Ligand is coordinated to metal ion by one oxygen atom of nitrogroup and one nitrogen atom of imidazole.

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